From 4-Methylenebut-2-en-4-olide to cis-Acetylacrylate

Graphic of the reaction.
Medline reference: Bruckmann M, Blasco R, Timmis KN, Pieper DH. J Bacteriol (1998) 180(2): 400-2.
Search Medline for dienelactone hydrolase.: 44 citations on June 26, 2008.

  4-Methylenebut-2-en-4-olide   
                |
                |  OH^-
   dienelactone | /
      hydrolase |/
       3.1.1.45 | Search GenBank, 460 hits on Sep. 22, 2008
          Kyoto |
         ExPASy |
                |
                v
       cis-Acetylacrylate

Generate a pathway starting from this reaction.

UM-BBD Biotransformation rules in accord with this reaction:: Dienelactone derivative -----> Maleylacetate derivative (bt0313)

[2,4-Dichlorophenoxyacetic Acid] [BBD Main Menu]

Page Author(s): Dong Jun Oh
August 14, 2005 Contact Us

This is the UM-BBD reaction, reacID# r0404.
It was generated on November 24, 2009 7:29:51 AM CST.

© 2009, University of Minnesota.